Environmental Pollution and Control II: Air Pollution Control — Settling Chambers, Cyclones, Wet Collectors, Fabric Filters and Electrostatic Precipitators, Control of Gaseous Pollutants, Indoor Air Pollution, Vehicular Emissions and Urban Air Quality — and Noise Pollution: Weighting Networks, Noise Indices, Noise Dose, Standards, Control and Vibration
2. Control of gaseous pollutants: adsorption, absorption, condensation and combustion
| Method | Principle | Typical application |
|---|---|---|
| Adsorption | Gas molecules adhere to the surface of a porous solid with a very large surface area, such as activated carbon, silica gel or zeolites; described by Freundlich and Langmuir isotherms; the bed is regenerated by steam or heat | Recovery of solvents and removal of VOCs and odours at low concentration |
| Absorption | The pollutant dissolves in, or reacts with, a liquid in a packed or spray tower | Wet limestone flue-gas desulphurisation (CaCO₃ + SO₂ + ½O₂ + 2H₂O → CaSO₄·2H₂O + CO₂, giving saleable gypsum); scrubbing of HCl, HF and ammonia |
| Condensation | Cooling or compressing the gas stream so that the vapour condenses | Pre-treatment of streams with high concentrations of recoverable solvents |
| Combustion | Oxidation of combustible pollutants to CO₂ and water by flaring, thermal incineration at about 700 to 1,000 °C with adequate time, temperature and turbulence (the "three Ts"), or catalytic combustion over platinum or palladium at about 250 to 500 °C | Destruction of VOCs, odours and carbon monoxide; catalytic units save fuel |
Nitrogen oxides are controlled first by combustion modification (low-NOx burners, staged air and fuel, flue-gas recirculation) and then by flue-gas treatment: selective catalytic reduction injects ammonia or urea over a vanadia-titania catalyst at about 300 to 400 °C, reducing NO to nitrogen and water (4NO + 4NH₃ + O₂ → 4N₂ + 6H₂O), while selective non-catalytic reduction injects them at about 900 to 1,100 °C without a catalyst, with lower efficiency. In December 2015 India notified emission standards for coal-fired thermal power plants covering particulate matter, sulphur dioxide, nitrogen oxides and mercury, which require flue-gas desulphurisation at many plants; the deadlines for compliance have been extended more than once.
3. Indoor air pollution, vehicular emissions and urban air quality
Indoor air pollution comes above all from burning solid fuels, wood, dung, crop residues, coal and kerosene, in open fires and simple stoves, which exposes women and young children to smoke laden with fine particles, carbon monoxide and carcinogens; the WHO attributes millions of deaths a year worldwide to household air pollution. Other indoor sources are tobacco smoke, formaldehyde from pressed-wood furniture and adhesives, VOCs from paints and cleaning products, radon from soil and building materials, nitrogen dioxide and carbon monoxide from gas heaters, and moulds and dust mites in damp buildings. Sick building syndrome describes headaches, eye and throat irritation and fatigue among occupants of poorly ventilated buildings that ease when they leave. Remedies are cleaner fuels such as LPG, promoted in India under the Pradhan Mantri Ujjwala Yojana (2016), improved stoves and chimneys, source control and better ventilation.
Vehicles emit carbon monoxide and unburnt hydrocarbons, mostly from petrol engines, and nitrogen oxides and particulate matter, mostly from diesel engines, together with benzene and other air toxics. Petrol cars use a three-way catalytic converter, whose platinum, palladium and rhodium oxidise CO and hydrocarbons and reduce NOx simultaneously; it works only near the stoichiometric air-fuel ratio of about 14.7:1, held by an oxygen sensor, and it is poisoned by lead, which is why unleaded petrol was a precondition. Diesel vehicles use an oxidation catalyst, a diesel particulate filter and selective catalytic reduction with urea. India's Bharat Stage norms, modelled on the European ones, were tightened in steps: Bharat Stage IV applied nationwide from April 2017, and the country then leapfrogged Stage V to apply Bharat Stage VI nationwide from 1 April 2020, with fuel of 10 ppm sulphur, cutting permitted NOx from diesel cars by about two-thirds and requiring particulate filters. Other measures are CNG for public transport, adopted in Delhi on the Supreme Court's directions, pollution-under-control certificates, fuel-quality improvement and incentives for electric vehicles.
Urban air quality results from the combination of emissions, from vehicles, industry, construction dust, road dust, waste burning and domestic fuel, with meteorology and topography. Most Indian cities exceed the national PM₁₀ standard. The National Clean Air Programme, launched in January 2019, set city-specific action plans for non-attainment cities, those that persistently fail the standards, with an initial goal of a 20 to 30% cut in particulate concentrations by 2024 against 2017, later revised to up to 40% by 2025–26, and links funding to measured improvement. Source apportionment studies, using emission inventories and receptor models that match the chemical fingerprints of particles to their sources, guide which measures to take in each city.
4. Noise: sources, decibels, weighting networks and noise indices
Noise is unwanted sound. Its main sources are road, rail and air traffic, industry and construction, loudspeakers and firecrackers, and domestic appliances. Because the ear responds to an enormous range of pressures, sound is measured on the logarithmic decibel scale: sound pressure level Lp = 20 log₁₀(p ÷ p₀), with p₀ = 20 µPa, the threshold of hearing, equivalent to 10 log₁₀(I ÷ I₀) for intensity. Levels therefore add logarithmically: L = 10 log₁₀ Σ 10^(Lᵢ/10). Two equal sources give 3 dB more than one (80 dB + 80 dB = 83 dB); three equal sources of 85 dB give 85 + 10 log₁₀ 3 ≈ 89.8 dB; and a source 10 dB quieter than another adds only about 0.4 dB. In the open, the level from a point source falls by about 6 dB for each doubling of distance and from a line source such as a busy road by about 3 dB.
Weighting networks filter a sound level meter's response to match human hearing, which is least sensitive at low and very high frequencies. The A-weighting approximates the ear at moderate levels and is used for almost all environmental and occupational standards, levels being written dB(A); C-weighting is nearly flat and is used for high levels and peak measurements; D-weighting was designed for aircraft noise; and Z (zero) weighting is unweighted. Because noise varies over time, it is summarised by statistical and energy-averaged indices.
| Index | Definition | Use |
|---|---|---|
| Leq | The steady level with the same acoustic energy as the fluctuating noise over the period: Leq = 10 log₁₀[(1/T) Σ tᵢ 10^(Lᵢ/10)] | The basis of Indian ambient noise standards |
| L10, L50, L90 | Levels exceeded for 10%, 50% and 90% of the time | L10 represents the peaks that cause annoyance, L50 the median and L90 the background |
| Ldn | The day-night average level, with a 10 dB penalty added to night-time levels | Community noise, recognising greater disturbance at night |
| TNI (traffic noise index) | TNI = 4(L10 − L90) + L90 − 30 | Traffic noise, weighting variability heavily because fluctuating noise annoys more than steady noise |
Two worked cases. A worker is exposed to 90 dB(A) for 2 hours and 70 dB(A) for 6 hours: Leq(8 h) = 10 log₁₀[(2 × 10⁹ + 6 × 10⁷) ÷ 8] = 10 log₁₀(2.575 × 10⁸) ≈ 84.1 dB(A), far above the arithmetic mean of 75 dB, because the loud period dominates the energy. At a roadside with L10 = 75 dB(A) and L90 = 60 dB(A), TNI = 4 × 15 + 60 − 30 = 90.
5. Noise dose, standards, control, vibration and health effects
Noise dose expresses occupational exposure against the permissible time at each level: D = Σ Cᵢ ÷ Tᵢ, where Cᵢ is the actual time spent at a level and Tᵢ the time permitted at it; a dose above 1 (100%) exceeds the limit. Under the common criterion of 90 dB(A) for 8 hours with a 5 dB exchange rate, the permitted time halves for each 5 dB increase, to 4 hours at 95 dB(A) and 2 hours at 100 dB(A). A worker spending 4 hours at 95 dB(A) and 2 hours at 90 dB(A) receives D = 4/4 + 2/8 = 1.25, which exceeds the limit. Ambient noise in India is governed by the Noise Pollution (Regulation and Control) Rules 2000, framed under the Environment (Protection) Act 1986.
| Area (Noise Pollution Rules 2000) | Day, 6 a.m. to 10 p.m., Leq dB(A) | Night, 10 p.m. to 6 a.m., Leq dB(A) |
|---|---|---|
| Industrial | 75 | 70 |
| Commercial | 65 | 55 |
| Residential | 55 | 45 |
| Silence zone (at least 100 m around hospitals, educational institutions and courts) | 50 | 40 |
The Rules also forbid loudspeakers and public address systems at night, from 10 p.m. to 6 a.m., except in closed premises, subject to limited relaxation by the state on a few days a year. Noise is controlled at the source, along the path and at the receiver. At the source: quieter machines, maintenance, vibration isolation mounts, enclosures and silencers. Along the path: distance, barriers and berms, absorptive linings and, to a small extent, dense green belts. At the receiver: ear plugs and muffs, soundproofed rooms and limiting exposure time by job rotation. Passive methods use materials and structures to absorb, block or isolate sound and work best at high frequencies; active noise control generates an anti-phase signal that cancels the noise by destructive interference and works best at low frequencies, as in noise-cancelling headphones and ducts.
Vibration is oscillatory motion transmitted through solids, measured with accelerometers as displacement, velocity or acceleration against frequency; for blasting and structural damage the peak particle velocity is the standard measure. Whole-body vibration, from vehicles and heavy machinery, is linked to back disorders, and hand-arm vibration from power tools causes hand-arm vibration syndrome, including vibration white finger, a vascular and nerve disorder. The effects of noise on health are auditory and non-auditory. Prolonged exposure above about 85 dB(A) causes noise-induced hearing loss, a permanent threshold shift that typically appears first as a dip in hearing near 4,000 Hz, preceded by temporary threshold shifts and often accompanied by tinnitus. Non-auditory effects include annoyance, interference with speech and learning, sleep disturbance, stress and raised blood pressure and cardiovascular risk.
Key takeaways
- Settling chambers and cyclones remove coarse particles cheaply; venturi scrubbers, fabric filters and ESPs remove fine particles; ESP efficiency is 1 − exp(−wA ÷ Q), and high-resistivity Indian fly ash causes back-corona.
- Gases are controlled by adsorption (activated carbon), absorption (limestone FGD to gypsum), condensation and thermal or catalytic combustion; NOx by low-NOx burners and SCR with ammonia.
- Solid-fuel cooking drives indoor pollution; three-way catalysts need stoichiometric mixtures and unleaded fuel; Bharat Stage VI applied nationwide from 1 April 2020, skipping Stage V; NCAP (2019) targets non-attainment cities.
- Decibels add logarithmically (two equal sources give +3 dB); A-weighting mimics the ear; Leq is energy-averaged, L10 peaks and L90 background; TNI = 4(L10 − L90) + L90 − 30.
- Noise dose D = Σ C ÷ T must not exceed 1; the 2000 Rules set 75/70, 65/55, 55/45 and 50/40 dB(A) for industrial, commercial, residential and silence zones by day and night; noise causes hearing loss with a 4 kHz dip, and vibration causes white finger.
Practice questions (10)
Attempt each one before opening the answer. Every explanation names the tempting wrong option as well as the right one, because that is where marks are lost.
An electrostatic precipitator has a collecting plate area of 3,000 m² and treats 100 m³/s of flue gas; the effective migration velocity of the particles is 0.1 m/s. Using the Deutsch-Anderson equation, what is its collection efficiency in per cent, to one decimal place?
Numerical answer — type the value.
Show answer
Answer: 95.0
η = 1 − exp(−wA ÷ Q) = 1 − exp(−0.1 × 3000 ÷ 100) = 1 − e⁻³ = 1 − 0.0498 = 0.9502, or 95.0%. Treating wA ÷ Q = 3 as the efficiency, or using e⁻³ itself (5.0%), are the usual slips.A worker is exposed to 90 dB(A) for 2 hours and 70 dB(A) for 6 hours in an 8-hour shift. What is the 8-hour Leq in dB(A), to one decimal place?
Numerical answer — type the value.
Show answer
Answer: 84.1
Leq = 10 log₁₀[(2 × 10^9.0 + 6 × 10^7.0) ÷ 8] = 10 log₁₀[(2 × 10⁹ + 0.06 × 10⁹) ÷ 8] = 10 log₁₀(2.575 × 10⁸) = 84.1 dB(A). The time-weighted arithmetic mean, (2 × 90 + 6 × 70) ÷ 8 = 75 dB, ignores the logarithmic scale and badly understates the exposure.Which particulate control device gives very high efficiency for fine particles with a very low pressure drop, but has a high capital cost and depends on the electrical resistivity of the dust?
Show answer
Answer: A — Electrostatic precipitator
ESPs charge particles in a corona and collect them on plates, with little resistance to gas flow, which suits the huge flows of power stations. Venturi scrubbers also capture fine particles but at a high pressure drop, and cyclones and settling chambers are poor for fine particles.Which statements about a three-way catalytic converter are correct? Select all that apply.
Show answer
Answer: A — It works efficiently only near the stoichiometric air-fuel ratio; B — It oxidises carbon monoxide and hydrocarbons; C — It reduces nitrogen oxides to nitrogen
The platinum, palladium and rhodium catalyst treats all three pollutants at once, but only in a narrow window around an air-fuel ratio of about 14.7:1, kept by an oxygen sensor. Lead coats and poisons the catalyst, which is why catalytic converters required unleaded petrol.Two machines each produce 80 dB at a point when running alone. When both run together, the level at that point is about
Show answer
Answer: D — 83 dB
Doubling the acoustic energy adds 10 log₁₀ 2 ≈ 3 dB, so 80 + 80 gives 83 dB. Decibels cannot be added arithmetically, which rules out 160 dB; 86 dB would need four equal sources.Assertion (A): Electrostatic precipitators at many Indian coal-fired power stations need larger plate areas or flue-gas conditioning. Reason (R): The low-sulphur, high-ash Indian coal produces fly ash of high electrical resistivity, which causes back-corona on the plates. Choose the correct option.
Show answer
Answer: A — Both A and R are true, and R is the correct explanation of A
Both are true and R explains A. With little sulphur trioxide in the flue gas, the ash layer on the plates conducts poorly, holds its charge and discharges back into the gas, lowering collection; injecting SO₃ or ammonia lowers resistivity, and larger plates compensate for the lower migration velocity.From what date did Bharat Stage VI emission norms apply nationwide in India?
Show answer
Answer: C — 1 April 2020
India leapfrogged from Bharat Stage IV, which applied nationwide from April 2017, directly to Stage VI from 1 April 2020, skipping Stage V, with 10 ppm sulphur fuel. The 2017 date belongs to BS IV.Which of the following correctly state ambient noise limits under the Noise Pollution (Regulation and Control) Rules 2000? Select all that apply.
Show answer
Answer: C — Silence zone, night: 40 dB(A); D — Residential area, day: 55 dB(A)
The limits (day/night, Leq dB(A)) are industrial 75/70, commercial 65/55, residential 55/45 and silence zone 50/40. So residential day 55 and silence night 40 are right; 45 is the residential night limit, not the industrial one, and 75 is the industrial day limit, not the commercial one.At a roadside monitoring point L10 is 75 dB(A) and L90 is 60 dB(A). What is the traffic noise index, TNI = 4(L10 − L90) + L90 − 30?
Numerical answer — type the value.
Show answer
Answer: 90
TNI = 4 × (75 − 60) + 60 − 30 = 60 + 30 = 90. The factor of 4 on the spread between L10 and L90 reflects the finding that fluctuating traffic noise is more annoying than a steady noise of the same average level.A worker spends 4 hours at 95 dB(A), where 4 hours are permitted, and 2 hours at 90 dB(A), where 8 hours are permitted. The noise dose is
Show answer
Answer: B — 1.25, which exceeds the permissible limit
D = Σ C ÷ T = 4/4 + 2/8 = 1 + 0.25 = 1.25. Any dose above 1 means the permitted exposure has been exceeded, even though each period taken separately looks acceptable.