Stratigraphy and the Geological Time Scale: Principles, Radiometric Dating, Radioactive Equilibrium, and the Stratigraphy and Resources of India
2. The geological time scale
The geological time scale divides the 4.54 Ga history of the Earth into eons, eras and periods. Phanerozoic divisions are defined by fossils (relative time) and given numerical ages by radiometric dating of volcanic ash layers and intrusions that bracket the fossil-bearing beds. Ages below are rounded and “about”; editions of the scale differ by a Ma or two. The eons are the Hadean (formation to about 4.0 Ga), Archaean (about 4.0 to 2.5 Ga), Proterozoic (2.5 Ga to about 540 Ma) and Phanerozoic (about 540 Ma to today). The first three form the Precambrian, about 88 per cent of Earth history. The Phanerozoic eras are the Paleozoic (about 540 to 250 Ma), Mesozoic (about 250 to 66 Ma) and Cenozoic (66 Ma to today).
| Period | Start (Ma) | A useful marker |
|---|---|---|
| Cambrian | 540 | Sudden abundance of shelled animals such as trilobites; base of the Phanerozoic |
| Ordovician | 485 | Diversification of marine invertebrates; end-Ordovician glaciation and extinction |
| Silurian | 445 | Earliest vascular land plants |
| Devonian | 420 | Age of fishes; first forests and early tetrapods |
| Carboniferous | 360 | Coal swamp forests of the northern continents; Gondwana glaciation begins |
| Permian | 300 | Glossopteris flora and glaciation in the south; end-Permian mass extinction at about 252 Ma |
| Triassic | 252 | Recovery from the extinction; dinosaurs and early mammals appear |
| Jurassic | 200 | Dinosaurs dominant; ammonites abundant; break-up of Gondwana begins |
| Cretaceous | 145 | Flowering plants spread; Deccan eruption and dinosaur extinction near its end at 66 Ma |
| Paleogene | 66 | Radiation of mammals; India–Asia collision at about 50 to 55 Ma |
| Neogene | 23 | Himalayan uplift and Siwalik molasse; spread of grasslands |
| Quaternary | 2.6 | Glacial and interglacial cycles; humans; alluvium |
3. Absolute time: the decay law and radiometric ages
Each unstable nucleus decays at random, but its probability of decay per unit time is a constant, the decay constant λ (unit: per year). The rate of decay is therefore proportional to the number of atoms present, dN/dt = −λN, and integration gives N = N₀e^(−λt). Temperature, pressure and chemical state do not change λ measurably for the decays used in dating, which is why decay is a dependable clock. The half-life is the time for N to fall to N₀/2: t½ = ln 2/λ = 0.693/λ. The mean life is τ = 1/λ = 1.443 t½. The activity A = λN is the number of decays per unit time. After n half-lives the fraction left is (½)ⁿ: ½, ¼, ⅛ and 6.25 per cent at n = 4.
Age equation. If a sample holds N parent atoms now and D* radiogenic daughter atoms, then D* = N₀ − N = N(e^(λt) − 1), so t = (1/λ) ln(1 + D*/N). Worked example: for a pair with t½ = 1.25 Ga, λ = 0.693/1.25 = 0.554 per Ga. A mineral with D*/N = 0.25 has t = ln(1.25)/0.554 = 0.223/0.554 = 0.40 Ga.
| Parent → daughter | Half-life | Typical use |
|---|---|---|
| U-238 → Pb-206 | about 4.47 Ga | Zircon and other uranium minerals; the oldest rocks and meteorites |
| U-235 → Pb-207 | about 0.70 Ga | Paired with U-238 as a cross-check |
| Th-232 → Pb-208 | about 14 Ga | Thorium-rich minerals such as monazite |
| Rb-87 → Sr-87 | about 49 Ga | Whole-rock and mineral isochrons of old granites and metamorphic rocks |
| K-40 → Ar-40 | about 1.25 Ga | Volcanic rocks and mica cooling ages; only about 11 per cent of K-40 decays give Ar-40, the rest give Ca-40 |
| C-14 → N-14 | 5730 years | Organic matter younger than about 50,000 years |
Choosing a method. The half-life should be comparable with, or longer than, the age to be measured: C-14 is useless for a 100 Ma rock, and the 49 Ga half-life of Rb-87 makes little daughter in a young rock. A mineral dates the moment it became a closed system: crystallisation for zircon, cooling below the closure temperature for argon in mica. The assumptions are no gain or loss of parent or daughter since closure, and a known or zero initial daughter.
Isochron. For Rb–Sr, ⁸⁷Sr/⁸⁶Sr = (⁸⁷Sr/⁸⁶Sr)₀ + (⁸⁷Rb/⁸⁶Sr)(e^(λt) − 1). Cogenetic samples with different Rb/Sr plot on a straight line, an isochron, whose slope is e^(λt) − 1 and whose intercept is the initial ratio, so the initial ratio need not be assumed. With λ = 1.42 × 10⁻¹¹ per year, a slope of 0.0143 gives t = ln(1.0143)/(1.42 × 10⁻¹¹) = 1.0 Ga.
4. Radioactive equilibrium: secular and transient
In a decay chain the daughter (N₂, λ₂) is fed by its parent (N₁, λ₁) and itself decays, dN₂/dt = λ₁N₁ − λ₂N₂. What happens depends on which half-life is longer.
| Case | Condition | Long-run result |
|---|---|---|
| Secular equilibrium | Parent half-life much longer than the daughter's (λ₁ ≪ λ₂) | Activities equal, λ₂N₂ = λ₁N₁, so N₂/N₁ = λ₁/λ₂ = t½(daughter)/t½(parent); reached after about 5 to 7 daughter half-lives |
| Transient equilibrium | Parent longer-lived than the daughter but comparably (λ₁ < λ₂) | N₂/N₁ = λ₁/(λ₂ − λ₁); activity ratio A₂/A₁ = λ₂/(λ₂ − λ₁) > 1; both then fall with the parent's half-life |
| No equilibrium | Parent shorter-lived than the daughter (λ₁ > λ₂) | The parent disappears first and the ratio never becomes constant |
Worked secular example: in a closed U-238 system (t½ = 4.47 × 10⁹ years), Ra-226 (t½ = 1600 years) settles at N(Ra)/N(U) = 1600/(4.47 × 10⁹) = 3.6 × 10⁻⁷ with equal activities. In an old, closed uranium ore every member of the series is in secular equilibrium with U-238, which is why the gamma rays of Bi-214 are used to estimate “equivalent uranium”. Loss of radon gas or leaching of uranium upsets the equilibrium, and the disequilibrium itself can date young (Quaternary) events. Worked transient example: parent t½ = 10 h, daughter t½ = 2 h gives A₂/A₁ = (1/2)/(1/2 − 1/10) = 1.25.
5. Major stratigraphic divisions of India (outline)
Peninsular India is built of old cratons, welded by mobile belts, overlain by little-deformed Proterozoic basins, then by the continental Gondwana basins, the Deccan lavas and, in the north, the young Himalayan sequence. Reading the table from top to bottom is, broadly, reading oldest to youngest (ages approximate, and some rows overlap in time).
| Division | Broad age | Character and examples |
|---|---|---|
| Archaean cratons: Dharwar, Bastar, Singhbhum, Bundelkhand, Aravalli | older than 2.5 Ga; some gneisses over 3 Ga | Gneiss and granitoid terrains with greenstone belts; Iron Ore Group banded iron formations; Dharwar belts with gold |
| Proterozoic mobile and fold belts: Aravalli–Delhi, Satpura, Eastern Ghats, Southern Granulite | mainly Proterozoic (Aravalli older than Delhi) | Deformed, metamorphosed supracrustal rocks; khondalite and charnockite in the granulite belts |
| Purana basins: Cuddapah, Vindhyan, Chhattisgarh, Kaladgi, Bhima | Proterozoic | Thick, almost unmetamorphosed sandstone, shale and limestone; Vindhyan groups Semri, Kaimur, Rewa, Bhander |
| Gondwana Supergroup (Damodar, Son, Mahanadi, Godavari valleys) | Late Carboniferous or Permian to Early Cretaceous | Mainly non-marine rocks in fault-bounded basins; glacial Talchir at the base, coal in Barakar and Raniganj, Glossopteris flora |
| Deccan Traps (older Rajmahal Traps in the east) | about 66 Ma (Rajmahal: Early Cretaceous) | Tholeiitic flood basalt flows; intertrappean beds between flows; dinosaur-bearing Lameta beds below; laterite and bauxite caps |
| Marine Mesozoic and Tertiary of the margins: Kutch, Cauvery, Narmada, Assam | Jurassic to Neogene | Fossiliferous marine beds, with Jurassic ammonites of Kutch; the Tertiary basins carry oil and gas |
| Himalaya: Tethys, Higher, Lesser, Siwalik (Sub-Himalaya) | Proterozoic to Pleistocene; collision about 50 to 55 Ma | Zones from north to south separated by the South Tibetan Detachment, Main Central Thrust, Main Boundary Thrust and Main Frontal Thrust; Siwalik molasse of Miocene to Pleistocene age |
| Quaternary | last 2.6 Ma | Indo-Gangetic alluvium (older Bhangar, younger Khadar), desert and coastal deposits |
6. Metallic ores, coal and petroleum of India (outline)
Resources follow geology. Metals sit in the old Precambrian terrains (Archaean greenstone belts, the Singhbhum and Aravalli belts, ultramafic bodies); coal sits in the Permian Gondwana basins; lignite and petroleum sit in young Tertiary basins. A craton of gneiss has no coal or oil, since both need a sedimentary basin and buried organic matter.
| Resource | Principal areas | Geological setting |
|---|---|---|
| Iron (haematite, magnetite) | Odisha and Jharkhand (Singhbhum), Chhattisgarh (Bailadila), Karnataka (Bellary–Hospet) | Banded iron formations of the Iron Ore Group and Dharwar belts |
| Manganese | Maharashtra and Madhya Pradesh (Nagpur–Balaghat), Odisha, Karnataka | Metamorphosed Precambrian manganese sediments (gondite of the Sausar Group); lateritic enrichment |
| Chromite | Sukinda, Odisha | Layered ultramafic bodies in Precambrian rocks |
| Copper | Khetri (Rajasthan), Singhbhum (Jharkhand), Malanjkhand (Madhya Pradesh) | Delhi-belt metasediments; Singhbhum shear zone; porphyry-type copper in granite at Malanjkhand |
| Lead and zinc | Rajasthan: Zawar, Rajpura–Dariba, Rampura–Agucha | Stratabound sulphides in the Precambrian metasediments of the Aravalli region |
| Gold | Kolar (now closed) and Hutti, Karnataka | Quartz veins in Dharwar greenstone belts |
| Bauxite | Odisha, Gujarat, Maharashtra, Jharkhand, Chhattisgarh | Lateritic weathering of khondalite and Deccan basalt (a supergene deposit) |
| Uranium and beach-sand minerals | Jaduguda (Singhbhum shear zone); coasts of Kerala, Tamil Nadu, Odisha | Shear-zone uranium; coastal placers of ilmenite, monazite, zircon, rutile |
Coal. Most Indian coal (well over nine-tenths of the reserves) is Permian Gondwana coal, bituminous to sub-bituminous and often high in ash, in the Barakar and Raniganj formations: the Damodar valley (Raniganj, Jharia with the main coking coal, Bokaro, Karanpura), the Son and Mahanadi valleys (Singrauli, Korba, Talcher) and the Godavari–Wardha valley (Singareni, Wardha). Tertiary coals of the north-east (Assam, Meghalaya) are young and high in sulphur, and lignite occurs at Neyveli (Tamil Nadu), in Gujarat and in Rajasthan. Rank rises as peat, lignite, sub-bituminous, bituminous, anthracite, with carbon content increasing.
Petroleum. India's oil and gas come from Tertiary sedimentary basins, with a few older ones: Assam–Arakan (Digboi, the oldest producing field, found in the late nineteenth century), Cambay (Gujarat), the western offshore (Mumbai High), Krishna–Godavari, Cauvery and Rajasthan (Barmer). A field needs a source rock, a porous reservoir, an impermeable seal and a trap such as an anticline, in the right order of timing.
Key takeaways
- Relative order comes from superposition, original horizontality, lateral continuity, cross-cutting, inclusions and faunal succession; unconformities mark missing time, and intrusions are dated by what they cut, not by position.
- Key boundaries: Archaean–Proterozoic about 2.5 Ga, Proterozoic–Phanerozoic about 540 Ma, end-Permian extinction about 252 Ma, Cretaceous–Paleogene about 66 Ma. Sediments are dated by bracketing ash beds, lavas and intrusions.
- Decay: N = N₀e^(−λt), t½ = 0.693/λ, mean life 1/λ, fraction (½)ⁿ after n half-lives. Age t = (1/λ) ln(1 + D/N), and D/N = 2ⁿ − 1. A Rb–Sr isochron has slope e^(λt) − 1 and an intercept equal to the initial ratio.
- Secular equilibrium (long-lived parent): equal activities and N₂/N₁ = λ₁/λ₂. Transient equilibrium (parent longer-lived but comparable): A₂/A₁ = λ₂/(λ₂ − λ₁) > 1. A shorter-lived parent gives no equilibrium.
- India from old to young: Archaean cratons, Proterozoic mobile belts and Purana basins, Gondwana (late Paleozoic to Early Cretaceous, glacial Talchir at the base), Deccan Traps (about 66 Ma), Himalaya with Siwalik molasse, Quaternary alluvium.
- Metals lie in Precambrian terrains (iron in banded formations, chromite at Sukinda, gold in Dharwar belts, base metals in Rajasthan), coal mainly in Permian Gondwana basins, and lignite and petroleum in Tertiary basins.
Practice questions (18)
Attempt each one before opening the answer. Every explanation names the tempting wrong option as well as the right one, because that is where marks are lost.
A basalt dyke cuts through a folded sandstone but is not seen in the conglomerate that rests with an angular unconformity on the eroded sandstone and dyke. What is the correct relative age order from oldest to youngest?
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Answer: A — Sandstone, then dyke, then conglomerate, because the dyke cuts the sandstone and was truncated by erosion first
The dyke cuts the sandstone, so it is younger than the sandstone (cross-cutting). It is truncated by the erosion surface and absent from the conglomerate, so it is older than the conglomerate. The tempting alternative places the dyke last because it is exposed alongside the upper beds; position in the pile dates layers, not intrusions. No rule makes igneous rock older than the sediment it intrudes.Which fossil is the most useful index fossil for correlating beds between two widely separated sedimentary basins?
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Answer: B — A species of short geological range that is abundant, easily identified and spread over many basins
A good index fossil has a short stratigraphic range, which gives fine time resolution, together with wide geographic spread, abundance and easy identification, so that the same time slice can be recognised in distant basins. A long-ranging widespread species is the tempting answer but dates a bed only to a broad interval; a rare or local species cannot correlate across basins.Which of the following statements about relative dating are correct?
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Answer: A — A fault is younger than the youngest bed that it displaces; B — Granite pebbles in an overlying conglomerate show that the granite is older than the conglomerate
A fault must be younger than every bed it cuts, and a pebble must exist before the conglomerate that contains it, so the granite is older. A sill is injected into already-formed rock, so it is younger than both beds, not coeval with the lower one. Tilted beds beneath younger horizontal sedimentary beds define an angular unconformity; a nonconformity has sedimentary rock resting on igneous or metamorphic rock.A charcoal sample retains 12.5 per cent of its original C-14 activity. Taking the half-life of C-14 as 5730 years, the age of the sample, in years, is ____.
Numerical answer — type the value.
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Answer: 17190
Fraction remaining = (1/2)ⁿ = 0.125 = 1/8, so n = 3 half-lives. Age = 3 × 5730 = 17190 years. Check with the decay law: t = ln(1/0.125)/λ = 2.0794/(ln 2/5730) = 17190 years.If the decay constant of a radioactive nuclide were twice that of another nuclide, how would its half-life compare with the other's?
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Answer: D — It would be half as long, because the half-life is inversely proportional to the constant
t½ = 0.693/λ, so doubling λ halves the half-life: the nuclide decays faster. The tempting answer reverses the proportionality. The half-life is not affected by temperature for the decays used in dating, and it is not related to the square of λ.A mineral contains radiogenic daughter atoms and surviving parent atoms in the ratio D*/N = 0.5. The parent has a half-life of 1.25 Ga. Use ln 2 = 0.693 and ln 1.5 = 0.405. The age of the mineral in Ga, to two decimal places, is ____.
Numerical answer — type the value.
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Answer: 0.73
λ = 0.693/1.25 = 0.5544 per Ga. t = (1/λ) ln(1 + D/N) = ln(1.5)/0.5544 = 0.405/0.5544 = 0.7305, which is 0.73 Ga. Using exact logarithms gives 0.7312, again 0.73. A common slip is to use ln(0.5), or to treat D/N = 0.5 as half of the parent having decayed, which would give one half-life.In one granite, zircons that contain no older inherited cores give a U–Pb age of 1.8 Ga, a whole-rock Rb–Sr isochron gives about 1.8 Ga, and biotite gives a K–Ar age of 1.0 Ga. What is the most reasonable interpretation?
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Answer: C — The granite crystallised about 1.8 Ga ago, and argon in biotite was lost during later reheating until the mineral cooled about 1.0 Ga ago
Different systems close at different temperatures. Zircons free of inherited cores and a whole-rock isochron both give the crystallisation age, while argon escapes from biotite at a much lower temperature, so the K–Ar age records cooling below the argon closure temperature after reheating or slow uplift. The alternatives fail: crystallisation at 1.0 Ga is excluded by zircons that have no inherited cores, decay constants do not change with heating, and mica does not crystallise earlier than zircon in a granite.A Rb–Sr isochron for a set of cogenetic rocks has a slope of 0.0288. Take the decay constant of Rb-87 as 1.42 × 10⁻¹¹ per year. The age of the rocks, in Ma, to the nearest 100 Ma, is ____.
Numerical answer — type the value.
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Answer: 2000
Slope = e^(λt) − 1, so λt = ln(1.0288) = 0.02839 and t = 0.02839/(1.42 × 10⁻¹¹) = 1.9995 × 10⁹ years, about 2000 Ma. The slope of an isochron is e^(λt) − 1 and not the age itself, so the logarithm must be taken before dividing by λ.Which of the following statements about radiometric dating are correct?
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Answer: A — For the decays used in dating, the half-life does not change with temperature or the host mineral's chemistry; C — The intercept of a Rb–Sr isochron gives the initial ⁸⁷Sr/⁸⁶Sr ratio of the cogenetic samples
Decay constants are insensitive to temperature and chemistry for these decays, and the isochron intercept is the initial ratio. After two half-lives one quarter of the parent remains, not none. C-14 is exhausted after a few tens of thousands of years and cannot date a rock hundreds of millions of years old.In an old, undisturbed, closed uranium ore, Ra-226 (half-life 1600 years) is in equilibrium with its long-lived ancestor U-238 (half-life 4.47 billion years). Which statement is correct?
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Answer: C — The two have equal activities, and the Ra-226 atoms are fewer than the U-238 atoms in the ratio of their half-lives
Because the parent half-life is vastly longer than the daughter's, the system is in secular equilibrium: λ₂N₂ = λ₁N₁, so the activities are equal and N₂/N₁ = λ₁/λ₂ = 1600/(4.47 × 10⁹) ≈ 3.6 × 10⁻⁷. The transient factor λ₂/(λ₂ − λ₁) is tempting but tends to 1 when λ₁ is negligible against λ₂. Equal atom numbers would give the daughter a much higher activity, which equilibrium excludes.A parent nuclide of half-life 4.0 × 10⁹ years decays to a daughter of half-life 8.0 × 10⁴ years, and the system has been closed for a very long time. The number of daughter atoms present per 10⁹ parent atoms is ____.
Numerical answer — type the value.
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Answer: 20000
The parent is vastly longer-lived, so secular equilibrium holds: N₂/N₁ = λ₁/λ₂ = t½(daughter)/t½(parent) = 8.0 × 10⁴/4.0 × 10⁹ = 2.0 × 10⁻⁵. Per 10⁹ parent atoms, N₂ = 2.0 × 10⁻⁵ × 10⁹ = 20000. Inverting the ratio would give 5 × 10¹³ daughter atoms, which is impossible because the shorter-lived daughter cannot outnumber its parent in secular equilibrium.A parent of half-life 12 h decays to a daughter of half-life 4 h, and transient equilibrium has been established. The ratio of the daughter's activity to the parent's activity, A₂/A₁, to one decimal place is ____.
Numerical answer — type the value.
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Answer: 1.5
In transient equilibrium A₂/A₁ = λ₂/(λ₂ − λ₁) = T₁/(T₁ − T₂) in terms of half-lives = 12/(12 − 4) = 1.5. Check with λ proportional to 1/T: λ₁ = 1/12 and λ₂ = 1/4, so (1/4)/(1/4 − 1/12) = 0.25/0.1667 = 1.5. The ratio exceeds 1 because the daughter's activity includes the feeding decays.The Talchir Formation at the base of the Gondwana Supergroup is characterised by which kind of deposit?
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Answer: D — Glacial boulder beds (tillite) from the late Paleozoic Gondwana glaciation
The Talchir Formation begins with a boulder bed of glacial origin (tillite) and shales, recording the late Paleozoic Gondwana glaciation. The coal-bearing units are the Barakar and Raniganj formations above it, which is the tempting confusion; the Jurassic marine beds are in Kutch, and the flood basalts are the Deccan Traps.Which of the following arranges these Indian units correctly from oldest to youngest: Siwalik Group, Deccan Traps, Vindhyan Supergroup, Dharwar greenstone belts?
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Answer: A — Dharwar greenstone belts, Vindhyan Supergroup, Deccan Traps, Siwalik Group
The Dharwar belts are Archaean to early Proterozoic, the Vindhyan basin is Proterozoic and unmetamorphosed, the Deccan Traps are about 66 Ma and the Siwalik molasse is Miocene to Pleistocene. The Vindhyan Supergroup rests on older basement and is younger than the Archaean greenstone belts, and the Siwaliks are the youngest of the four because they record the rise of the Himalaya.Which of the following statements about the Himalayan divisions are correct?
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Answer: A — The Siwalik Group lies between the Main Frontal Thrust and the Main Boundary Thrust; B — The Main Central Thrust separates the Lesser Himalaya from the Higher Himalaya; C — The Tethys Himalaya lies north of the Higher Himalaya and contains thick marine sedimentary successions
From south to north the zones are Siwalik (between the Main Frontal and Main Boundary Thrusts), Lesser Himalaya (between the Main Boundary and Main Central Thrusts), Higher Himalaya (between the Main Central Thrust and the South Tibetan Detachment) and Tethys Himalaya with its marine successions. The statement placing the Lesser Himalaya against the South Tibetan Detachment describes the Higher Himalaya instead.A survey must choose, for a first search for coal, the terrain that is geologically most promising. Which one should it choose?
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Answer: B — A fault-bounded Permian Gondwana basin such as the Damodar valley, with Barakar-type beds
Coal needs a sedimentary basin in which plant matter accumulated and was buried, and Permian Gondwana basins such as the Damodar valley hold most Indian coal. Gneiss terrains and Higher Himalayan crystalline rocks are metamorphic and contain no coal; lava flows bury and destroy plant matter rather than preserving coal, although coal-bearing sediments may lie beneath them.A closed mineral contains seven daughter atoms of radiogenic origin for every one parent atom now present, and no daughter was present at the start. How many half-lives of the parent have elapsed?
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Answer: B — 3 half-lives, since the parent is now one-eighth of its original amount
D/N = 7 means that originally there were 7 + 1 = 8 parent-equivalents, so N/N₀ = 1/8 = (1/2)³ and three half-lives have passed; in general D/N = 2ⁿ − 1. Using log₂ 7 = 2.8 forgets the surviving parent, which is the common error. Four half-lives would give D*/N = 15, and each half-life does not produce one daughter per parent.Which of the following pairs of an Indian resource and its principal geological host are correct?
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Answer: A — Chromite of Sukinda, Odisha: ultramafic bodies within a Precambrian terrain; B — Coking coal of Jharia: Permian Gondwana coal measures of the Damodar valley; C — Gold of Kolar, Karnataka: quartz veins in an Archaean Dharwar greenstone belt
Sukinda chromite sits in ultramafic bodies in Precambrian rocks, Jharia coking coal in the Permian Gondwana coal measures, and Kolar gold in quartz veins of an Archaean greenstone belt. Petroleum needs a sedimentary basin with source, reservoir and seal; the Mumbai High lies in a Tertiary sedimentary basin of the western offshore, not in crystalline gneiss.