Mechanical Properties: Elasticity, Slip, Strengthening, Fracture, Fatigue, Creep and Composites
2. Perfect-crystal shear strength, slip and Schmid’s law
Frenkel’s estimate. Slide one plane of atoms over the next: the shear stress is periodic in the displacement x, τ = τ_max sin(2πx/b), where b is the atomic spacing along the slip direction and a the spacing between the planes. For small x, Hooke’s law gives τ = Gγ = Gx/a. Equating the slopes at x = 0: τ_max·2π/b = G/a, so τ_th = Gb/(2πa) ≈ G/2π ≈ G/6 for b ≈ a (better potentials give about G/30 to G/10). For copper, G ≈ 48 GPa, so the estimate is several GPa, yet a pure annealed copper crystal yields at a critical resolved shear stress of about 0.5 MPa, thousands of times lower.
The gap is closed by dislocations. A dislocation moves the slipped region forward one row of atoms at a time, so only the few bonds along the line are strained at once, like moving a carpet by pushing a ripple. The lattice friction (Peierls stress) is smallest on close-packed planes in close-packed directions, where planes are widest apart and b is smallest; these are the slip systems. The plastic shear rate follows the Orowan equation, γ̇ = ρ_m b v̄, with ρ_m the density of mobile dislocations and v̄ their mean speed.
| Structure | Slip plane and direction | Number of systems |
|---|---|---|
| FCC (Al, Cu, Ni) | {111} ⟨110⟩: 4 planes × 3 directions | 12 |
| BCC (α-Fe, W) | {110} ⟨111⟩: 6 planes × 2 directions (also {112}, {123} at higher temperature) | 12 on {110} |
| HCP (Mg, Zn) | Basal (0001) ⟨11-20⟩: 1 plane × 3 directions | 3 |
Schmid’s law. Pull a single crystal with force F on cross-section A₀, so σ = F/A₀. Let φ be the angle between the load axis and the slip-plane normal, and λ the angle between the load axis and the slip direction. The slip plane has area A₀/cos φ and the force component along the slip direction is F cos λ, so the resolved shear stress is τ_R = σ cos φ cos λ. Slip starts when τ_R reaches the critical resolved shear stress τ_CRSS, a material constant at given temperature and purity: σ_y = τ_CRSS/(cos φ cos λ). The Schmid factor m = cos φ cos λ has a maximum of 0.5 at φ = λ = 45°. Worked example: τ_CRSS = 0.5 MPa and φ = 40°, λ = 50° give m = 0.766 × 0.643 = 0.49, so σ_y ≈ 1.0 MPa.
3. Strengthening: strain, solute, precipitate and grain size
Every strengthening mechanism works the same way: it puts obstacles in the path of dislocations, so a higher stress is needed to keep them moving. None of them changes E. The Taylor relation for forest hardening is Δτ = αGb√ρ, with ρ the dislocation density (m⁻²) and α a constant of order 0.2 to 0.5.
| Mechanism | Obstacle and relation | Cost and limit |
|---|---|---|
| Strain (work) hardening | Dislocations multiply and tangle; ρ rises with plastic strain; σ_y ∝ √ρ | Ductility falls; removed by recrystallisation on annealing |
| Solid-solution hardening | Solute strain fields (size misfit) interact with dislocations; strength rises with solute content and misfit | Electrical conductivity drops sharply |
| Precipitation hardening | Fine particles: small coherent ones are sheared; large hard ones are bypassed by bowing, Δτ ≈ Gb/L for spacing L | Peak at a critical size; over-ageing coarsens particles and softens |
| Grain-size refinement | Boundaries stop dislocations, which pile up; σ_y = σ₀ + k_y d^(−1/2) | Only mechanism that raises strength and toughness; fails at high temperature (creep) |
Hall-Petch worked example. Take σ₀ = 50 MPa and k_y = 0.6 MPa·m^(1/2). For d = 25 µm, d^(−1/2) = (25 × 10⁻⁶)^(−1/2) = 200 m^(−1/2), so σ_y = 50 + 0.6 × 200 = 170 MPa. For d = 6.25 µm (four times smaller), d^(−1/2) = 400, so σ_y = 50 + 240 = 290 MPa: reducing d fourfold doubles the grain-boundary term, not the whole yield stress.
4. Stress concentration and Griffith’s theory of fracture
Stress concentration. For an elliptical hole in a plate under remote tension σ, with semi-axis a perpendicular to the load and b along it, the stress at the tip is σ_tip = σ(1 + 2a/b) = σ(1 + 2√(a/ρ_t)), where ρ_t = b²/a is the tip radius. A circular hole (a = b) gives 3σ; a sharp crack, with ρ_t of atomic size, gives enormous concentration. A ductile metal blunts the tip by yielding; a ceramic or glass cannot, so it fails at a nominal stress far below its theoretical strength σ_th ≈ √(Eγ_s/a₀) of order E/10.
Griffith energy balance. A crack extends only if the elastic energy released at least pays for the new surface. For a thin plate under plane stress with an internal crack of total length 2a, per unit thickness: elastic energy released = πσ²a²/E, surface energy added = 4aγ_s (two faces of length 2a). Total energy U = U₀ − πσ²a²/E + 4aγ_s. Setting dU/da = 0 gives −2πσ²a/E + 4γ_s = 0, so σ_f = √(2Eγ_s/(πa)), with a the half-length. For plane strain replace E by E/(1 − ν²). Equivalent statement: fracture at K = σ√(πa) = K_c, with K_c = √(2Eγ_s).
Reading the result. σ_f ∝ a^(−1/2), so doubling the flaw length lowers the fracture stress to 1/√2 = 0.71 of its value, and strength is set by the largest flaw. For glass with E = 70 GPa, γ_s = 1.0 J/m² and a = 10 µm: σ_f = √(2 × 70 × 10⁹ × 1.0/(π × 10 × 10⁻⁶)) = √(4.46 × 10¹⁵) ≈ 67 MPa, close to what scratched glass actually carries. Cracks close under compression, which is why ceramics are strong in compression and weak in tension. In metals and polymers plastic work γ_p ≫ γ_s, and the Orowan-Irwin modification replaces γ_s by (γ_s + γ_p); pure Griffith theory is for brittle solids.
5. Fatigue: cyclic loading, S-N curve, initiation and propagation
Fatigue is failure under repeated stress, often at a maximum stress below the yield stress. For a stress cycle: σ_m = (σ_max + σ_min)/2 (mean), σ_a = (σ_max − σ_min)/2 (amplitude), Δσ = σ_max − σ_min (range) = 2σ_a, and the stress ratio R = σ_min/σ_max (R = −1 for fully reversed loading). Example: σ_max = 300 MPa and σ_min = −100 MPa give σ_m = 100 MPa, σ_a = 200 MPa and R = −1/3.
The S-N curve plots stress amplitude against the number of cycles to failure N_f on a logarithmic axis. Steels and titanium alloys show an endurance (fatigue) limit σ_e, a plateau below which life is effectively infinite (for steels often about half the tensile strength). Aluminium, copper and magnesium alloys show none; their fatigue strength is quoted at a stated life such as 10⁸ cycles. The finite-life region is a straight line on log σ_a against log N (Basquin form σ_a = A N^(−b)). Example: 600 MPa at 10³ cycles and 300 MPa at 10⁶ give b = log(600/300)/3 = 0.100, so at 400 MPa, N = 10³ × (600/400)^(1/0.1) ≈ 5.7 × 10⁴ cycles.
- Initiation. Cyclic slip concentrates in persistent slip bands at the surface, producing intrusions and extrusions that become micro-cracks, usually at a notch, scratch, inclusion or corner. Stage I growth runs along a crystallographic shear plane for a few grains.
- Propagation. In Stage II the crack grows perpendicular to the maximum tensile stress, one striation per cycle. The Paris law gives the rate in the steady region, da/dN = C(ΔK)^m, with ΔK = YΔσ√(πa) and m typically 2 to 4 for ductile metals. Doubling Δσ multiplies the rate by 2^m.
- Final fracture is sudden overload when K_max reaches K_c on the reduced section; the surface shows smooth beach marks and a rough final zone. Life improves with polished surfaces, compressive residual stress (shot peening, case hardening), generous fillet radii and lower tensile mean stress; corrosion shortens it.
6. Creep: stages and mechanisms
Creep is slow, time-dependent plastic strain under constant stress, significant above roughly 0.4 T_m (absolute temperature) for metals, as in turbine blades, boilers and steam pipes. The strain-time curve has three stages: primary (rate falling, hardening beats recovery), secondary (steady-state, the minimum creep rate, hardening and recovery balanced; this is the design quantity) and tertiary (rate rising through necking, internal voids and grain-boundary cracking, ending in rupture). A creep test at constant load drifts into tertiary partly because the true stress rises as the section thins.
Steady-state rate. ε̇_s = A σⁿ exp(−Q_c/RT), an Arrhenius form. In lattice-diffusion-controlled creep Q_c is close to the activation energy of self-diffusion. Raising T from T₁ to T₂ at constant σ multiplies the rate by exp[(Q_c/R)(1/T₁ − 1/T₂)]. Example: Q_c = 300 kJ/mol, 800 K to 900 K, with R = 8.314 J/mol·K: exp[(300000/8.314)(1/800 − 1/900)] = exp(5.01) ≈ 150, so a 100 K rise multiplies the rate about 150 times. For rupture, the Larson-Miller parameter P = T(C + log₁₀ t_r), with T in kelvin, t_r in hours and C ≈ 20, is constant for a given stress; so 1000 h at 900 K (P = 20 700) equals about 2.3 × 10⁴ h at 850 K.
| Mechanism | Stress exponent n and grain-size dependence | Path and regime |
|---|---|---|
| Dislocation (power-law) creep: glide plus climb | n ≈ 3 to 8; no grain-size dependence | Lattice diffusion; high stress |
| Nabarro-Herring creep | n = 1; rate ∝ 1/d² | Lattice diffusion through grains; high T, low stress |
| Coble creep | n = 1; rate ∝ 1/d³ | Grain-boundary diffusion; fine grains, lower T |
7. Composites: particle and fibre reinforcement; rule of mixtures
A composite joins a matrix (metal, ceramic or polymer) with a reinforcement to give properties neither has alone. Particle-reinforced composites include large-particle types, where particles share the load (concrete, WC-Co cermets), and dispersion-strengthened types, with fine particles (10 to 100 nm) that block dislocations like precipitates. Fibre-reinforced composites use continuous aligned, short or random fibres (glass, carbon, aramid in polymer matrices); the stiff, strong fibres carry the load and the matrix transfers it, with fibres needed longer than the critical length l_c = σ_f d/(2τ_c), where d is the fibre diameter, σ_f the fibre strength and τ_c the interfacial shear strength.
Rule of mixtures for an aligned continuous-fibre composite with volume fractions V_f and V_m = 1 − V_f. Loading along the fibres (iso-strain, Voigt, upper bound): fibre and matrix strain equally, E_∥ = E_f V_f + E_m V_m, and the load shares as F_f/F_m = E_f V_f/(E_m V_m). Loading across the fibres (iso-stress, Reuss, lower bound): both carry the same stress, 1/E_⊥ = V_f/E_f + V_m/E_m. Density is a simple weighted mean, ρ_c = ρ_f V_f + ρ_m V_m. Any particle composite lies between these two bounds.
Worked example: glass fibres (E_f = 70 GPa) in epoxy (E_m = 3 GPa), V_f = 0.5. E_∥ = 0.5 × 70 + 0.5 × 3 = 36.5 GPa. E_⊥ = 1/(0.5/70 + 0.5/3) = 1/(0.00714 + 0.1667) = 5.75 GPa. The fibre carries 35/36.5 = 96 percent of the axial load, yet across the fibres the composite is only about twice as stiff as the matrix. Aligned composites are strongly anisotropic.
Key takeaways
- Elastic modulus follows the curvature of the interatomic potential at r₀ (E ≈ S₀/r₀) and is insensitive to microstructure; yield strength is the opposite.
- Frenkel gives τ_th ≈ G/2π; real crystals yield 10³ to 10⁴ times lower because dislocations move one row at a time. Slip occurs on close-packed planes and directions, and starts when σ cos φ cos λ = τ_CRSS (Schmid factor ≤ 0.5).
- All strengthening mechanisms obstruct dislocations: Taylor Δτ = αGb√ρ for strain hardening, misfit fields for solutes, shearing or Orowan bowing (Gb/L) for precipitates, and σ_y = σ₀ + k_y d^(−1/2) for grain refinement, the only one that also toughens.
- Griffith: σ_f = √(2Eγ_s/(πa)) for an internal crack of length 2a; strength scales as a^(−1/2) and is set by the largest flaw. For ductile solids use γ_s + γ_p.
- Fatigue life splits into initiation at the surface and Stage II propagation obeying da/dN = C(ΔK)^m, then overload fracture; only ferrous and titanium alloys have an endurance limit.
- Creep has primary, secondary (minimum rate) and tertiary stages; ε̇ = Aσⁿ exp(−Q_c/RT); dislocation creep is d-independent, Nabarro-Herring goes as d⁻², Coble as d⁻³. Composite modulus lies between iso-strain (E_f V_f + E_m V_m) and iso-stress bounds.
Practice questions (18)
Attempt each one before opening the answer. Every explanation names the tempting wrong option as well as the right one, because that is where marks are lost.
Crystals A and B have the same bonding energy per atom (the same depth of the potential well U(r)), but the well of A is narrower, with a larger curvature (d²U/dr²) at the equilibrium separation r₀ than the well of B. Their equilibrium spacings are equal. Which statement about their Young’s moduli is correct?
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Answer: C — E_A > E_B, because E ≈ S₀/r₀ and the bond stiffness S₀ is the curvature of U(r) at r₀
For small displacements the force is F ≈ −S₀(r − r₀) with S₀ = (d²U/dr²) at r₀, and E ≈ S₀/r₀ for equal spacings. The narrower well has the larger S₀ and therefore the larger modulus. The tempting answer that the depth fixes E confuses bond energy with bond stiffness; the two correlate in real materials only because deep wells are usually steep as well. The modulus is structure-insensitive, so dislocation density does not fix it.Frenkel’s model for a perfect crystal predicts a shear strength of about G/2π, but annealed pure metal crystals yield at a stress thousands of times smaller. What is the accepted resolution of this discrepancy?
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Answer: A — Slip occurs by dislocation glide, which strains only the bonds along the line at any instant, not a whole plane at once
The Frenkel estimate assumes the whole plane slides over its neighbour at once. Dislocations let the slipped region advance one atom row at a time, so the stress needed is controlled by the lattice friction of the moving line and is orders of magnitude lower. G of real crystals is what it is (tens of GPa for metals) and vacancies are far too dilute to weaken all bonds.At room temperature a polycrystal of an HCP metal such as magnesium is much less ductile than a polycrystal of an FCC metal such as copper. Which reason is correct?
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Answer: D — Easy slip is confined to three basal systems, fewer than the five independent systems an arbitrary shape change needs
The basal plane (0001) with three ⟨11-20⟩ directions is close-packed and easy, but gives only two independent systems; a polycrystal needs five to follow arbitrary shape changes of grains without cracking, and the non-basal systems have a much higher critical stress at room temperature. HCP does have close-packed planes and glide along close-packed directions, so the other reasons misstate the structure.A single crystal is loaded in uniaxial tension along an axis perpendicular to the slip direction of a given slip system (so λ = 90°). Which statement about slip on that system is correct?
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Answer: B — No slip occurs on that system at any tensile stress, because cos λ = 0 makes the resolved shear stress zero
τ_R = σ cos φ cos λ, and cos 90° = 0, so τ_R = 0 for every σ; the system is inactive and other systems must operate. The maximum Schmid factor of 0.5 needs φ = λ = 45°. τ_CRSS is a material constant for the given temperature and purity; it does not depend on orientation, and a load perpendicular to the slip direction produces no shear force along it.Among the four classical routes of strengthening a metal (strain hardening, solid-solution hardening, precipitation hardening and grain-size refinement), which is generally credited with raising the yield strength and the toughness together?
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Answer: C — Grain-size refinement, because more boundaries block both dislocation motion and crack extension
Finer grains raise σ_y through σ₀ + k_y d^(−1/2) and also make cracks change direction at boundaries, so toughness generally rises along with strength. Strain hardening and precipitation hardening, and usually solid-solution hardening, reduce ductility and toughness to some degree; none of them removes stress concentrations.An age-hardenable alloy is held at a fixed ageing temperature and its hardness is measured against time. It rises to a peak and then falls. Which explanation of the fall (over-ageing) is correct?
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Answer: A — The precipitates coarsen and their spacing L grows, so dislocations bow between them more easily, Δτ ≈ Gb/L
At constant temperature below the solvus the particles grow (coarsen) while their number density falls, so L increases; once particles are large enough that dislocations bypass them by Orowan bowing, the strengthening Gb/L falls with increasing L. Dissolution would need a temperature above the solvus, ageing does not multiply dislocations, and modulus is nearly unaffected by ageing.A glass plate with an internal crack of total length 2a fractures in tension at stress σ_f. An identical plate has an internal crack of total length 8a. Using the Griffith criterion for the same plane-stress conditions, its fracture stress is
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Answer: D — σ_f/2, because σ_f ∝ a^(−1/2) and the crack length has increased fourfold
σ_f = √(2Eγ_s/(πa)) ∝ a^(−1/2). Going from 2a to 8a multiplies a by 4, so σ_f becomes σ_f/√4 = σ_f/2. The energy released grows as a² but the surface energy grows as a, and balancing them gives the inverse square root; the stress concentration argument alone would give a different, wrong, dependence.Continuous aligned carbon fibres (E_f = 230 GPa) occupy a volume fraction of 0.60 in an epoxy matrix (E_m = 3.0 GPa). The composite is loaded perpendicular to the fibres and the two phases carry the same stress (iso-stress). Its modulus in that direction, in GPa, is closest to
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Answer: B — 7.4, from 1/E = V_f/E_f + V_m/E_m
Iso-stress gives 1/E⊥ = 0.60/230 + 0.40/3.0 = 0.002609 + 0.13333 = 0.13594 GPa⁻¹, so E⊥ = 7.36 GPa, about 7.4. The 139 GPa value is the iso-strain (axial) bound, the most tempting wrong choice; transverse loading is dominated by the soft matrix, so the modulus stays close to that of the epoxy.A component is cycled between a maximum stress of 240 MPa (tension) and a minimum stress of −60 MPa (compression). Its stress amplitude σ_a and stress ratio R = σ_min/σ_max are
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Answer: C — σ_a = 150 MPa and R = −0.25, because the amplitude is half the range
The range is 240 − (−60) = 300 MPa, the amplitude is half of it, 150 MPa, the mean stress is (240 − 60)/2 = 90 MPa, and R = σ_min/σ_max = −60/240 = −0.25. The 300 MPa choice is the range, the 90 MPa choice is the mean, and R = −4 inverts the definition.A fine-grained ceramic creeps at a moderate temperature and low stress by Coble creep, in which atoms diffuse along grain boundaries and the strain rate is linear in stress. If the grain size is doubled with temperature and stress unchanged, the creep rate becomes
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Answer: A — 1/8 of its value, since Coble creep rate varies as d⁻³
Coble creep (grain-boundary diffusion) has ε̇ ∝ σ D_gb/d³, so doubling d divides the rate by 2³ = 8. The d⁻² law belongs to Nabarro-Herring creep (lattice diffusion), the tempting alternative; the stem names grain-boundary diffusion. Only dislocation (power-law) creep is independent of grain size.Which of the following statements about strengthening mechanisms are correct?
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Answer: A — Plastic deformation raises the dislocation density, and the resulting strain hardening makes σ_y rise roughly as √ρ; B — In solid-solution hardening the strain field around a misfitting solute atom interacts elastically with dislocations and hinders their glide; C — Grain boundaries strengthen because dislocations pile up against them and cannot pass easily into a neighbouring grain of different orientation
Taylor hardening gives Δτ = αGb√ρ; solute fields and grain boundaries obstruct glide as described. The precipitation statement is false: strength peaks at a critical particle size and falls on over-ageing as particles coarsen and the spacing L grows, so longer ageing does not always strengthen.Which of the following statements about creep of a crystalline metal at constant stress and high temperature are correct?
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Answer: A — In primary creep the strain rate falls with time because strain hardening outpaces recovery; B — In secondary (steady-state) creep the nearly constant rate reflects a balance between hardening and recovery
The statements on the primary and secondary stages are the standard description. Dislocation (power-law) creep has n of about 3 to 8 and no grain-size dependence; n = 1 and grain-size dependence belong to diffusional creep. Tertiary creep is an accelerating stage caused by necking, voids and grain-boundary cracking, ending in rupture.Which of the following are expected to lengthen the fatigue life of a steel shaft cycled at a fixed stress amplitude?
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Answer: B — Shot peening the surface to introduce compressive residual stress; D — Polishing the surface to remove scratches and machining marks
Fatigue cracks start at the surface at stress raisers. Compressive residual stress lowers the effective tensile part of the cycle, and polishing removes the micro-notches where cracks start. Sharp corners raise the local stress, and tensile residual stress adds to the mean stress, so both shorten life.A single crystal is pulled in uniaxial tension. The angle between the tensile axis and the slip-plane normal is 60° and the angle between the tensile axis and the slip direction is 45°. The critical resolved shear stress is 12.0 MPa. The tensile stress at which slip begins is ____ MPa (answer to one decimal place).
Numerical answer — type the value.
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Answer: 33.9
Schmid factor m = cos 60° × cos 45° = 0.5 × 0.7071 = 0.3536. Slip begins when σ m = τ_CRSS, so σ = 12.0/0.3536 = 33.94 MPa, which is 33.9 to one decimal place.A polycrystalline metal obeys the Hall-Petch relation σ_y = σ₀ + k_y d^(−1/2) with d the mean grain diameter in mm. Its yield stress is 160 MPa for d = 0.0625 mm and 250 MPa for d = 0.0100 mm. Its yield stress for d = 0.0016 mm (1.6 µm) is ____ MPa (answer as a whole number).
Numerical answer — type the value.
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Answer: 475
d^(−1/2) = 4 mm^(−1/2) for 0.0625 mm and 10 for 0.0100 mm. Then k_y = (250 − 160)/(10 − 4) = 15 MPa·mm^(1/2) and σ₀ = 160 − 15 × 4 = 100 MPa. For d = 0.0016 mm, d^(−1/2) = 1/0.04 = 25, so σ_y = 100 + 15 × 25 = 475 MPa.A thin glass plate (plane stress) contains an internal through-thickness crack of total length 2a = 2.0 µm. Take E = 70 GPa and surface energy γ_s = 1.0 J/m², and use the Griffith criterion σ_f = √(2Eγ_s/(πa)) with a the half-length of the crack. The fracture stress is ____ MPa (answer as a whole number).
Numerical answer — type the value.
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Answer: 211
The half-length is a = 1.0 µm = 1.0 × 10⁻⁶ m. σ_f = √(2 × 70 × 10⁹ × 1.0/(π × 1.0 × 10⁻⁶)) = √(4.456 × 10¹⁶) = 2.111 × 10⁸ Pa = 211 MPa. Using the full length 2.0 µm for a would give 149 MPa, the common slip.In the finite-life region of a steel’s S-N curve, log σ_a varies linearly with log N. The stress amplitude is 400 MPa at N = 10⁴ cycles and 300 MPa at N = 10⁶ cycles. The base-10 logarithm of the fatigue life N at a stress amplitude of 340 MPa is ____ (answer to two decimal places).
Numerical answer — type the value.
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Answer: 5.13
Slope: log σ_a falls by log(400/300) = 0.12494 over 2 decades of N, so the exponent is b = 0.06247 per decade. From 400 MPa to 340 MPa, log(400/340) = 0.07058. Additional decades of life = 0.07058/0.06247 = 1.1298. So log N = 4 + 1.1298 = 5.13 (N ≈ 1.35 × 10⁵ cycles).Continuous aligned glass fibres (E_f = 70 GPa) make up 40 percent by volume of a polymer-matrix composite (E_m = 3.0 GPa). The composite is loaded along the fibre direction and the fibres and matrix strain equally. Its elastic modulus is ____ GPa (answer to one decimal place).
Numerical answer — type the value.
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Answer: 29.8
Iso-strain loading gives E_∥ = E_f V_f + E_m V_m = 70 × 0.40 + 3.0 × 0.60 = 28.0 + 1.8 = 29.8 GPa.